Acrolein → HCID 69466373, compound

HRID 1794567Notes

Reaction equation

HRID 1794567 reaction equation
[C:1]([N:5]1[C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=2[O:7][C:6]1=[O:14])(=[O:4])[CH2:2][CH3:3].[CH:15]([CH:17]=[CH2:18])=[O:16]>>[CH3:3][C@H:2]([C@@H:15]([OH:16])[CH:17]=[CH2:18])[C:1]([N:5]1[C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][C:8]=2[O:7][C:6]1=[O:14])=[O:4]

Participants

3

Reactant 2

HCID 7847AcroleinHCID 8437913-Propionyl-2-benzoxazolinone

Product 1

HCID 69466373HCID 69466373, compound

Procedure

This compound was prepared according to the procedure of paragraph C, by reaction of N-propionyl-2-benzoxazolone with acrolein. 1H-NMR (CDCl3, 400 MHz) δ 8.06 (m, 1 H), 7.27–7.20 (m, 2 H), 5.91 (ddd, J=17,10, 5 Hz). 5.37 (dt, J=1, 17 Hz, 1 H), 5.24 (dt, J=1, 10 Hz, 1 H), 4.60 (m, 1 H), 4.06 (dq, J=3, 6 Hz, 1 H), 2.62 (d, J=4 Hz, 1 H), 1.30 (d, 6 Hz, 3 H). 13C-NMR (CDCl3, 100 MHz) δ 175.4, 151.1, 142.2, 137.2, 127.7, 125.5, 124.9, 116.6, 116.2, 109.9, 72.7, 44.0, 10.7.

Workup

  1. customThis compound was prepared

Sources & evidence

ORD record
ord-9a35e35071cb4e82b6154f936debc37d
Source dataset
uspto-grants-2006_04
Patent number
US07022825B2

Reaction notes

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