HCID 22177406, compound → HCID 22177418, compound

HRID 1797348Notes

Reaction equation

HRID 1797348 reaction equation
[CH3:1][C:2]1([CH3:69])[O:7][CH2:6][C:5]([C:9]([O:11][CH2:12][C:13]([CH2:56][O:57][C:58]([C:60]2([CH3:68])[CH2:65][O:64][C:63]([CH3:67])([CH3:66])[O:62][CH2:61]2)=[O:59])([CH3:55])[C:14]([O:16][CH2:17][C:18]([CH2:23][O:24][C:25](=[O:54])[C:26]([CH2:41][O:42][C:43]([C:45]2([CH3:53])[CH2:50][O:49][C:48]([CH3:52])([CH3:51])[O:47][CH2:46]2)=[O:44])([CH2:28][O:29][C:30]([C:32]2([CH3:40])[CH2:37][O:36][C:35]([CH3:39])([CH3:38])[O:34][CH2:33]2)=[O:31])[CH3:27])([CH3:22])[C:19]([OH:21])=[O:20])=[O:15])=[O:10])([CH3:8])[CH2:4][O:3]1.[N+:70]([C:73]1[CH:74]=[C:75]([CH:91]=[C:92]([N+:94]([O-:96])=[O:95])[CH:93]=1)[C:76]([O:78][CH2:79][CH2:80][CH2:81][CH2:82][CH2:83][CH2:84][CH2:85][CH2:86][CH2:87][CH2:88][CH2:89]Br)=[O:77])([O-:72])=[O:71]>>[CH3:66][C:63]1([CH3:67])[O:64][CH2:65][C:60]([C:58]([O:57][CH2:56][C:13]([CH2:12][O:11][C:9]([C:5]2([CH3:8])[CH2:6][O:7][C:2]([CH3:69])([CH3:1])[O:3][CH2:4]2)=[O:10])([CH3:55])[C:14]([O:16][CH2:17][C:18]([CH2:23][O:24][C:25](=[O:54])[C:26]([CH2:28][O:29][C:30]([C:32]2([CH3:40])[CH2:33][O:34][C:35]([CH3:38])([CH3:39])[O:36][CH2:37]2)=[O:31])([CH2:41][O:42][C:43]([C:45]2([CH3:53])[CH2:50][O:49][C:48]([CH3:51])([CH3:52])[O:47][CH2:46]2)=[O:44])[CH3:27])([CH3:22])[C:19]([O:21][CH2:89][CH2:88][CH2:87][CH2:86][CH2:85][CH2:84][CH2:83][CH2:82][CH2:81][CH2:80][CH2:79][O:78][C:76](=[O:77])[C:75]2[CH:74]=[C:73]([N+:70]([O-:72])=[O:71])[CH:93]=[C:92]([N+:94]([O-:96])=[O:95])[CH:91]=2)=[O:20])=[O:15])=[O:59])([CH3:68])[CH2:61][O:62]1

Participants

3

Reactant 2

HCID 22177406HCID 22177406, compoundHCID 22177449HCID 22177449, compound

Product 1

HCID 22177418HCID 22177418, compound

Procedure

Preparation can be carried out analogously to Example 1 using 10.19 g (9.81 mmol) 2,2-bis[({2,2-bis[({(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyl}oxy)methyl]propanoyl}oxy)methyl]propanoic acid, 1.494 g (9.81 mmol) 1,8-diazabicyclo[5.4.0]undec-7-ene(l,5-5) (DBU) and 4.81 g (10.79 mmol) 11-bromoundecyl 3,5-dinitrobenzoate, to yield 11-[(3,5-dinitrobenzoyl)oxy]undecyl 2,2-bis[({2,2-bis[({(2,2,5-trimethyl-1,3-dioxan-5-yl)carbonyl}oxy)methyl]propanoyl}oxy)methyl]propanoate.

Workup

  1. customPreparation

Sources & evidence

ORD record
ord-8738befdcf534d2084f8f4a81fa8bb14
Source dataset
uspto-grants-2006_04
Patent number
US07034098B2

Reaction notes

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