Boronic Acid → 3-(6'-Benzylamino-[2,2';4',3'']terpyridin-5''-yl)-phenol

HRID 1798522Notes

Reaction equation

HRID 1798522 reaction equation
[CH2:1]([NH:8][C:9]1[N:14]=[C:13]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][N:16]=2)[CH:12]=[C:11]([C:21]2[CH:22]=[N:23][CH:24]=[C:25]([C:27]3[CH:32]=[CH:31][CH:30]=[C:29]([O:33]C)[CH:28]=3)[CH:26]=2)[CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.COC1C=C(B(O)O)C=CC=1.B(O)O>>[CH2:1]([NH:8][C:9]1[N:14]=[C:13]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][N:16]=2)[CH:12]=[C:11]([C:21]2[CH:22]=[N:23][CH:24]=[C:25]([C:27]3[CH:28]=[C:29]([OH:33])[CH:30]=[CH:31][CH:32]=3)[CH:26]=2)[CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 61668Boronic AcidHCID 2734370(3-Methoxyphenyl)boronic acidHCID 44136848Benzyl-[5''-(3-methoxy-phenyl)-[2,2';4',3'']terpyridin-6'-yl]-amine

Product 1

HCID 687352943-(6'-Benzylamino-[2,2';4',3'']terpyridin-5''-yl)-phenol

Procedure

This compound is prepared analogously to Benzyl-[5″-(3-methoxy-phenyl)-[2,2′;4′,3″]terpyridin-6′-yl]-amine (Example 2.43) by 3-methoxyphenylboronic acid with the appropriate boronic acid.

Sources & evidence

ORD record
ord-95209c13dcc7448bbbce9ee113031738
Source dataset
uspto-grants-2013_01
Patent number
US08343966B2

Reaction notes

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