Phenol → Benzyl-{5''-[3-(2-dimethylamino-ethoxy)-phenyl]-[2,2';4',3'']terpyridin-6'-yl}-amine

Participants

Role	Name	HCID	Charge
Reactant	Phenol	HCID 996	—
Reactant	3-(6'-Benzylamino-[2,2';4',3'']terpyridin-5''-yl)-phenol	HCID 68735294	—
Reactant	Methyl-{5''-[3-(2-pyrrolidin-1-yl-ethoxy)-phenyl]-[2,2';4',3'']terpyridin-6'-yl}-amine	HCID 68757059	—
Product	Benzyl-{5''-[3-(2-dimethylamino-ethoxy)-phenyl]-[2,2';4',3'']terpyridin-6'-yl}-amine	HCID 68735736	—

Reaction Steps

This compound is prepared analogously to Methyl-{5″-[3-(2-pyrrolidin-1-yl-ethoxy)-phenyl]-[2,2′;4′,3″]terpyridin-6′-yl}-amine (Example 2.189) by replacing methylamino-[2,2′;4′,3″]terpyridin-5″-yl)-phenol (example 2.189 step 1) with 3-(6′-Benzylamino-[2,2′;4′,3″]terpyridin-5″-yl)-phenol (Example 2.143) and by replacing 1-(2-Chloro-ethyl)-pyrrolidine with 2-Dimethyl-aminoethyl chloride.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08343966B2
Source dataset	uspto-grants-2013_01
ORD ID	ord-e5c42c6a0d944bbd9c67e8fef15c3f22
Source note	uspto-grants-2013_01