Phosphorus tribromide → HCID 66933088, compound

Participants

Reaction Conditions

Reaction Steps

A solution of PBr3 (8.4 g, 31 mmol) in CH2Cl2 (40 ml) was added to the mixture of F13 (5.0 g, 15.5 mmol) in CH2Cl2 (30 ml) at 0° C. The resulting mixture was stirred for 10 minutes at 0° C. and then for 2 hour at room temperature before quenching with a saturated aqueous NaHCO3 solution to pH 8. The mixture was added to CH2Cl2 and the organic layer was separated, washed with water, dried over Na2SO4, and concentrated to obtain the title compound (5.2 g, 86.8%), mp: 98˜100° C. which was used without further purification.

Provenance & Evidence