2-Acetylpyridine → HCID 68636022, compound

HRID 1802805Notes

Reaction equation

HRID 1802805 reaction equation
Cl.[O:2]([C:9]1[CH:14]=[CH:13][C:12]([NH:15]N)=[C:11]([N+:17]([O-:19])=[O:18])[CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:20]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][N:24]=1)(=O)[CH3:21]>>[N+:17]([C:11]1[CH:10]=[C:9]([O:2][C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=2)[CH:14]=[C:13]2[C:12]=1[NH:15][C:20]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][N:24]=1)=[CH:21]2)([O-:19])=[O:18]

Participants

3

Reactant 2

HCID 142862-AcetylpyridineHCID 68636229HCID 68636229, compound

Product 1

HCID 68636022HCID 68636022, compoundYield 16%

Procedure

(4-Phenoxy-2-nitrophenyl)hydrazine hydrochloride (10 g, 49 mmol) and 2-acetylpyridine (5.5 ml, 49 mmol) were reacted according to the same procedures as Preparations 4 to 5 to give the title compound (2 g, Yield 16%).

Sources & evidence

ORD record
ord-c1d3e17375214d76af516d7017f24321
Source dataset
uspto-grants-2013_01
Patent number
US08349885B2

Reaction notes

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