HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 3-bromoperylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Perylene | HCID 9142 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 3-bromoperylene | HCID 11809703 | 56.5% |
Reaction Steps
Following the scheme shown in FIG. 18, perylene (252 mg, 1 mmol) was dissolved in DMF (45 ml), and a solution of NBS (178 mg) dissolved in DMF (10 ml) was added gradually. This was agitated at room temperature for 24 hours. H2O (200 ml) was added, and the product was precipitated and suction filtered. The product was recrystallized with hexane to obtain yellow-brown compound (1) (187 mg, mixture).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08354515B2 |
| Source dataset | uspto-grants-2013_01 |
| ORD ID | ord-400ad061558948afa531065f93e087cf |
| Source note | uspto-grants-2013_01 |