HRID1811693

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10613979

3,6-Dibromothieno[3,2-b]thiophene

C6H2Br2S2

结构：CCC[CH2][Sn]([CH2]CCC)([CH2]CCC)[c]1cnc([C@@H]2CCCN2C(=O)OC(C)(C)C)n1C(=O)OC(C)(C)C

HCID67240181

未命名化合物

结构：COC(=O)N[C@H](C(=O)N1CCC[C@H]1c1ncc(-c2ccc(-c3cc4sc(-c5cnc([C@@H]6CCCN6C(=O)OC(C)(C)C)[nH]5)cc4s3)cc2)[nH]1)C(C)C

HCID67240543

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)N1CCC[C@H]1c1nc(-c2csc3c(Br)csc23)cn1C(=O)OC(C)(C)C

HCID58310397

未命名化合物

PROCEDURE

实验过程

Compound 76 was synthesized from 3,6-dibromothieno[3,2,b]thiophene (6.71 mmol) and compound 61 (6.71 mmol), following the procedure as described for compound 63 to give compound 76 as a yellow crystal. MS (ESI, EI+) m/z=554-556 (MH+).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8c203d3bf6c241aa89fed8d89ee5326e
来源数据集: uspto-grants-2013_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08362068B2
来源说明: uspto-grants-2013_01

反应 SMILES

Br[C:2]1[C:3]2[S:9][CH:8]=[C:7]([Br:10])[C:4]=2[S:5][CH:6]=1.[C:11]([O:15][C:16]([N:18]1[C:22]([Sn](CCCC)(CCCC)CCCC)=[CH:21][N:20]=[C:19]1[C@@H:36]1[CH2:40][CH2:39][CH2:38][N:37]1[C:41]([O:43][C:44]([CH3:47])([CH3:46])[CH3:45])=[O:42])=[O:17])([CH3:14])([CH3:13])[CH3:12].C(OC(N1CCC[C@H]1C1NC(C2SC3C=C(C4C=CC(C5NC([C@@H]6CCCN6C(=O)[C@@H](NC(OC)=O)C(C)C)=NC=5)=CC=4)SC=3C=2)=CN=1)=O)(C)(C)C>>[C:11]([O:15][C:16]([N:18]1[CH:22]=[C:21]([C:2]2[C:3]3[S:9][CH:8]=[C:7]([Br:10])[C:4]=3[S:5][CH:6]=2)[N:20]=[C:19]1[C@@H:36]1[CH2:40][CH2:39][CH2:38][N:37]1[C:41]([O:43][C:44]([CH3:47])([CH3:46])[CH3:45])=[O:42])=[O:17])([CH3:14])([CH3:13])[CH3:12]