2-(2-chlorobenzenesulfonyl) acetonitrile → 2-(2-Chlorobenzene-1-sulfonyl)-3,3-di(methanesulfonyl)prop-2-enenitrile

HRID 1813894Notes

Reaction equation

HRID 1813894 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[S:8]([CH2:11][C:12]#[N:13])(=[O:10])=[O:9].ClC1C=C[C:18]([S:21]([CH2:24]C#N)(=[O:23])=[O:22])=CC=1>>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[S:8]([C:11](=[C:24]([S:8]([CH3:3])(=[O:10])=[O:9])[S:21]([CH3:18])(=[O:23])=[O:22])[C:12]#[N:13])(=[O:10])=[O:9]

Participants

3

Reactant 2

HCID 7182462-(2-chlorobenzenesulfonyl) acetonitrileHCID 7358292-(4-Chlorobenzenesulfonyl)acetonitrile

Product 1

HCID 225044652-(2-Chlorobenzene-1-sulfonyl)-3,3-di(methanesulfonyl)prop-2-enenitrile

Procedure

The titled compound was prepared in an analogous fashion to Intermediate 2 except that 2-(2-chlorobenzenesulfonyl) acetonitrile is utilized in place of 2-(4-chlorobenzenesulfonyl) acetonitrile.

Sources & evidence

ORD record
ord-fcb8dd93ac3346b6b6701f8b8fc6a3c5
Source dataset
uspto-grants-2005_04
Patent number
US06875771B2

Reaction notes

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