Methyl 3-(2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethyl-cyclopropane carboxylate → cis Methyl 3-(2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethyl-cyclopropane carboxylate

HRID 1814408Notes

Reaction equation

HRID 1814408 reaction equation
[Cl:1][C:2]([Cl:17])([C:13]([F:16])([F:15])[F:14])[CH2:3][CH:4]1[CH:6]([C:7]([O:9][CH3:10])=[O:8])[C:5]1([CH3:12])[CH3:11]>ClCCl>[Cl:1][C:2]([Cl:17])([C:13]([F:14])([F:16])[F:15])[CH2:3][C@@H:4]1[C@H:6]([C:7]([O:9][CH3:10])=[O:8])[C:5]1([CH3:12])[CH3:11]

Participants

3

Reactant 1

HCID 12942377Methyl 3-(2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethyl-cyclopropane carboxylate

Product 1

HCID 131724825cis Methyl 3-(2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethyl-cyclopropane carboxylate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Polarimetry of the methyl 3-(2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethyl-cyclopropane carboxylate in dichloromethane (5.84 gm/liter at 20° C.) gave an ∝D=+10.3°.

Sources & evidence

ORD record
ord-48403e7e93994437932e737823f6791a
Source dataset
uspto-grants-2005_04
Patent number
US06875885B2

Reaction notes

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