HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrylic Acid → Cyclohexanecarboxylic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrylic Acid | HCID 6581 | — |
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | Cyclohexyl phenyl ketone | HCID 12837 | — |
| Reactant | 3-Cyclohexene-1-carboxylic acid | HCID 20903 | — |
| Product | Cyclohexanecarboxylic acid | HCID 7413 | — |
Reaction Steps
In the synthesis mechanism of cyclohexyl phenyl ketone, a [2+4] Diels-Alder reaction using a 1,3-butadiene and an acrylic acid is carried out in the presence or absence of a solvent under the condition that no side reaction occurs, to prepare a 3-cyclohexene-1-carboxylic acid. The 3-cyclohexene-1-carboxylic acid is subjected to a hydrogenation reaction to yield a cyclohexanecarboxylic acid with a high conversion rate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06881865B2 |
| Source dataset | uspto-grants-2005_04 |
| ORD ID | ord-ac3330276105459f96048282b9dfca6e |
| Source note | uspto-grants-2005_04 |