HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromo-3-nitrotoluene → HCID 22493351, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromo-3-nitrotoluene | HCID 231828 | — |
| Reactant | 2-(Tri-n-butylstannyl)thiophene | HCID 2779373 | — |
| Product | HCID 22493351 | HCID 22493351 | 62% |
Reaction Steps
2-Bromo-3-nitrotoluene (3.35 g, 15.5 mmol) and 2-(tributylstannyl)-thiophene (5.7 g, 15.3 mmol, 1.0 eq) were coupled as in Example 75 to give 2.08 g of 2-(2-methyl-6-nitrophenyl)thiophene, which was reduced under conditions similar to Example 64 to give 1.4 g of 3-methyl-2-(2-thienyl)aniline.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06884801B1 |
| Source dataset | uspto-grants-2005_04 |
| ORD ID | ord-437cfcee3f1145a5b118fd6bbe8920a2 |
| Source note | uspto-grants-2005_04 |