2-Cyclohexen-1-one, 4,4-dimethyl- → Cyclohexanone, 4,4-dimethyl-

HRID 1816338Notes

Reaction equation

HRID 1816338 reaction equation
[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH:4]=[CH:3]1.[H][H]>C(O)C.[Pd]>[CH3:1][C:2]1([CH3:9])[CH2:7][CH2:6][C:5](=[O:8])[CH2:4][CH2:3]1

Participants

5

Reactant 2

HCID 1368392-Cyclohexen-1-one, 4,4-dimethyl-HCID 178418361HCID 178418361, compound

Product 1

HCID 138166Cyclohexanone, 4,4-dimethyl-Yield 98.7%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

To a solution of 4,4-dimethyl-2-cyclohexen-1-one (10 g) in ethanol (100 ml) was added 10% palladium on carbon (1 g), and hydrogen gas at atmosphere pressure for 4 hours. To the reaction mixture was filtered. The filtrate was concentrated by evaporation under reduced pressure to give 4,4-dimethylcyclohexanone (10.03 g).

Workup

  1. filtrationTo the reaction mixture was filtered
  2. concentrationThe filtrate was concentrated by evaporation under reduced pressure

Sources & evidence

ORD record
ord-ea54733e29f64adeb2cef9676ffb89d0
Source dataset
uspto-grants-2005_04
Patent number
US06884774B2

Reaction notes

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