HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Acetylcyclohexene → 3-Amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Acetylcyclohexene | HCID 13612 | — |
| Reactant | Ammonium Acetate | HCID 517165 | — |
| Reactant | 5-(4-(Dimethylamino)phenyl)-1,3-cyclohexanedione | HCID 730117 | — |
| Product | 3-Amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one | HCID 57883327 | — |
Reaction Steps
In analogy to (Baraldi, P. G.; Simoni, D.; Manfredini, S.; Synthesis 1983, (11) 902-903) hexahydro-naphthalene-1,3-dione (prepared from 1-cyclohex-1-enyl-ethanone according to (Chuang; Tien. Chem. Ber. 1936; 69; 25-29) was reacted with ammonium acetate to give the title compound as a colorless solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07598384B2 |
| Source dataset | uspto-grants-2009_10 |
| ORD ID | ord-8bf160331b8c4914824225b871c6041a |
| Source note | uspto-grants-2009_10 |