HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl propiolate → 6,7,8,9,9a,10-hexahydrobenzo[g]quinoline-2,5(1H,5aH)-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl propiolate | HCID 13536 | — |
| Reactant | 5-Oxo-2-thioxo-1,2,5,6,7,8-hexahydroquinoline-3-carbonitrile | HCID 1849967 | — |
| Reactant | 3-Amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one | HCID 57883327 | — |
| Product | 6,7,8,9,9a,10-hexahydrobenzo[g]quinoline-2,5(1H,5aH)-dione | HCID 57883270 | — |
Reaction Steps
In close analogy to (Pettit, G. R.; Fleming, W. C.; Paull, K. D. J. Org. Chem. 1968, 33 (3) 1089-1092), 3-amino-4a,5,6,7,8,8a-hexahydro-4H-naphthalen-1-one was reacted with methyl propiolate to give the title compound as a colorless solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07598384B2 |
| Source dataset | uspto-grants-2009_10 |
| ORD ID | ord-0b07600102b44f55a31d3e78bbcf28ef |
| Source note | uspto-grants-2009_10 |