6,7-Dimethyl-2,3-dihydro-1H-inden-1-one → HCID 68877785, compound

Participants

Reaction Steps

6,7-Dimethyl-1-indanone (2.50 g, 15.60 mmol), NaBH3CN (6.90 g, 0.11 mol) and NH4OAc (36.00 g, 0.47 mol) in isopropanol were reacted according to the protocols as outlined in general procedure E to afford the title indanamine. Spectroscopic data: 1H NMR (300 MHz, CDCl3) δ 1.6 (br s, 2H), 1.83-1.96 (m, 1H), 2.01-2.11 (m, 1H), 2.26 (s, 3H), 2.31 (s, 3H), 2.72-2.87 (m, 1H), 3.05-3.18 (m, 1H), 4.42-4.50 (m, 1H), 6.95-7.09 (m, 2H).

Provenance & Evidence