Chloroform → HCID 87588252, compound

Participants

Reaction Steps

4-octyloxyphenylphenyl iodonium chloride (15.34 g) was dissolved in water and THF in a beaker and a solution of potassium perfluorobutane sulfonate (11.67 g) in water and THF solution was added on stirring. After six hours, chloroform (200 ml) was added and stirred for 3 hours. The chloroform layer was washed several times with water, dried over anhydrous sodium sulfate, filtered, evaporated to oil which was added to hexane (500 ml), and a precipitate formed. The precipitate was filtered and re-dissolved in dichloromethane and precipitated in hexane, filtered, dried in the vacuum oven, yielding 22.0 g of product.

Provenance & Evidence