HRID1821294

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=S(=O)(c1ccccc1)n1c(-c2cccc(CO)c2)cc2c(Br)ccnc21

HCID58980081

未命名化合物

$结构：C=C(/C=C\C(=C/C)c1nn(CCN(C)C(=O)OC(C)(C)C)cc1B1OC(C)(C)C(C)(C)O1)[N+](=O)[O-]$

HCID86617392

未命名化合物

PRODUCTS

生成物

结构：CN(CCn1cc(-c2ccnc3c2cc(-c2cccc(CO)c2)n3S(=O)(=O)c2ccccc2)c(-c2ccc([N+](=O)[O-])cc2)n1)C(=O)OC(C)(C)C

HCID69456341

未命名化合物

PROCEDURE

实验过程

Following the procedure described for Intermediate 100 using {3-[4-bromo-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridin-2-yl]phenyl}methanol and 1,1-dimethylethyl {2-[3-[(1E,2Z)-1-ethylidene-4-nitro-2,4-pentadien-1-yl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazol-1-yl]ethyl}methylcarbamate provided the title compound. ESMS [M+H]+: 709.2.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4de0bebf206947c6808c97ff16da7cd6
来源数据集: uspto-grants-2009_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07605266B2
来源说明: uspto-grants-2009_10

反应 SMILES

Br[C:2]1[CH:7]=[CH:6][N:5]=[C:4]2[N:8]([S:19]([C:22]3[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=3)(=[O:21])=[O:20])[C:9]([C:11]3[CH:12]=[C:13]([CH2:17][OH:18])[CH:14]=[CH:15][CH:16]=3)=[CH:10][C:3]=12.[CH:28](=[C:30](/[C:38]1[C:42](B2OC(C)(C)C(C)(C)O2)=[CH:41][N:40]([CH2:52][CH2:53][N:54]([CH3:62])[C:55](=[O:61])[O:56][C:57]([CH3:60])([CH3:59])[CH3:58])[N:39]=1)\[CH:31]=[CH:32]/[C:33]([N+:35]([O-:37])=[O:36])=C)\[CH3:29]>>[OH:18][CH2:17][C:13]1[CH:12]=[C:11]([C:9]2[N:8]([S:19]([C:22]3[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=3)(=[O:20])=[O:21])[C:4]3=[N:5][CH:6]=[CH:7][C:2]([C:42]4[C:38]([C:30]5[CH:31]=[CH:32][C:33]([N+:35]([O-:37])=[O:36])=[CH:29][CH:28]=5)=[N:39][N:40]([CH2:52][CH2:53][N:54]([CH3:62])[C:55](=[O:61])[O:56][C:57]([CH3:59])([CH3:58])[CH3:60])[CH:41]=4)=[C:3]3[CH:10]=2)[CH:16]=[CH:15][CH:14]=1