Tetracyclododecene → Tcd ccmn

HRID 1823193Notes

Reaction equation

HRID 1823193 reaction equation
[CH:1]12[CH:10]3[CH2:11][CH:7]([CH2:8][CH2:9]3)[CH:6]1[CH:5]1[CH2:12][CH:2]2[CH:3]=[CH:4]1.[C:13]([C:16]1([CH2:23][C:24]([OH:26])=[O:25])[CH2:21][CH:20]2[CH2:22][CH:17]1[CH:18]=[CH:19]2)([OH:15])=[O:14]>>[CH:1]12[CH:10]3[CH2:11][CH:7]([CH2:8][CH2:9]3)[CH:6]1[CH:5]1[CH2:12][CH:2]2[CH:3]=[CH:4]1.[C:13]([C:16]1([CH2:23][C:24]([OH:26])=[O:25])[CH2:21][CH:20]2[CH2:22][CH:17]1[CH:18]=[CH:19]2)([OH:15])=[O:14]

Participants

3

Reactant 2

HCID 136844TetracyclododeceneHCID 303490CID 303490

Product 1

HCID 131725725Tcd ccmn

Procedure

The same polymerization as in Example 7 was carried out, except for using a mixture of 15 parts of tetracyclo[4.4.0.12,5.17,10]dodec-3-ene (TCD) and 18.4 parts of 5-carboxy-5-carboxymethyl-2-norbornene (CCMN) obtained in Preparation Example 4 as monomers (monomer composition: TCD/CCMN=50/50 (mol/mol)), and using 1-hexene in an amount of 0.16 part. The polymerization conversion rate was 98%, the monomer composition ratio (TCD/CCMN) in the resulting ring-opened copolymer was 50/50 (mol/mol), and the weight average molecular weight (Mw) was 34,400.

Workup

  1. customThe same polymerization as in Example 7

Sources & evidence

ORD record
ord-c0c2f77e061d463c8850fa61f307bd9c
Source dataset
uspto-grants-2006_05
Patent number
US07037993B2

Reaction notes

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