HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetracyclododecene → Tcd cmcmn
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetracyclododecene | HCID 136844 | — |
| Reactant | 5-Carboxy-5-methoxycarbonylmethyl-2-norbornene | HCID 22172288 | — |
| Product | Tcd cmcmn | HCID 131725726 | — |
Reaction Steps
The same polymerization as in Example 2 was carried out, except for using a mixture of 15 parts of tetracyclo[4.4.0.12,5.17,10]dodec-3-ene (TCD) and 19.7 parts of 5-carboxy-5-methoxycarbonylmethyl-2-norbornene (CMCMN) obtained in Preparation Example 5 as monomers (monomer composition: TCD/CMCMN=50/50 (mol/mol)). The polymerization conversion rate was 99% or more, the monomer composition ratio (TCD/CMCMN) in the resulting ring-opened copolymer was 50/50 (mol/mol), and the weight average molecular weight (Mw) was 36,100.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07037993B2 |
| Source dataset | uspto-grants-2006_05 |
| ORD ID | ord-51c3c72508244a51a47d1ce7262603eb |
| Source note | uspto-grants-2006_05 |