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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1823194Generated: October 27, 2026

Tetracyclododecene → Tcd cmcmn

https://huagongshe.com/reaction/1823194

Reaction equation

Participants

RoleNameHCIDCharge
ReactantTetracyclododeceneHCID 136844—
Reactant5-Carboxy-5-methoxycarbonylmethyl-2-norborneneHCID 22172288—
ProductTcd cmcmnHCID 131725726—

Reaction Steps

The same polymerization as in Example 2 was carried out, except for using a mixture of 15 parts of tetracyclo[4.4.0.12,5.17,10]dodec-3-ene (TCD) and 19.7 parts of 5-carboxy-5-methoxycarbonylmethyl-2-norbornene (CMCMN) obtained in Preparation Example 5 as monomers (monomer composition: TCD/CMCMN=50/50 (mol/mol)). The polymerization conversion rate was 99% or more, the monomer composition ratio (TCD/CMCMN) in the resulting ring-opened copolymer was 50/50 (mol/mol), and the weight average molecular weight (Mw) was 36,100.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07037993B2
Source datasetuspto-grants-2006_05
ORD IDord-51c3c72508244a51a47d1ce7262603eb
Source noteuspto-grants-2006_05