HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 22172362, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-Bromo-6-methoxycarbonylnaphthalene | HCID 854134 | — |
| Reactant | 2,4,6-Trivinylboroxin-Pyridine Complex | HCID 2734806 | — |
| Catalyst | HCID 178418397 | HCID 178418397 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | HCID 22172362 | HCID 22172362 | 98.1% |
Reaction Steps
Methyl 6-bromo-2-naphthalene carboxylate (98 g) was dissolved in dimethoxyethane (2 1) and tetrakis(triphenylphosphine)palladium (44 g) was added in nitrogen atmosphere. The mixture was stirred for 30 minutes at room temperature. Potassium carbonate (52 g), water (1 1) and 2,4,6-trivinylcyclotriboroxane-pyridine complex (91 g) were added and the mixture was stirred for 24 hours while refluxing with heating. There action mixture was cooled to room temperature and treated with activated alumina to obtain methyl 2-vinyl-6-naphthalene carboxylate (77 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07037994B2 |
| Source dataset | uspto-grants-2006_05 |
| ORD ID | ord-3c64090ec318462abb36a7d794fa46a3 |
| Source note | uspto-grants-2006_05 |