Methacrylic Acid → HCID 68649066, compound

HRID 1823707Notes

Reaction equation

HRID 1823707 reaction equation
[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:7]([O:12][CH2:13][CH:14]=[CH2:15])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:16]([O:21][CH2:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)(=[O:20])[C:17]([CH3:19])=[CH2:18].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>COCC(O)C.O>[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:7]([O:12][CH2:13][CH:14]=[CH2:15])(=[O:11])[C:8]([CH3:10])=[CH2:9].[C:16]([O:21][CH2:22][C:23]1[CH:24]=[CH:25][CH:26]=[CH:27][CH:28]=1)(=[O:20])[C:17]([CH3:19])=[CH2:18]

Participants

7

Reactant 4

HCID 4093Methacrylic Acid2×HCID 7274Allyl methacrylateHCID 17236Benzyl methacrylateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)

Product 1

HCID 68649066HCID 68649066, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 79001-Methoxy-2-propanolSolvent2×

Conditions

Temperature
70 °C

Procedure

405 parts of 1-methoxy-2-propanol were charged in a reaction vessel and heated under a nitrogen flow so that the internal temperature of the vessel was 70° C. Then a solution in which 16.0 parts of methacrylic acid, 25.1 parts of allyl methacrylate, 49.0 parts of benzyl methacrylate (composition ratio of these methacrylic acid and esters thereof was 28:30:42 in molar ratio), 3.29 parts of V-65 (2,2′-azobis-(2,4′-dimethylvaleronitrile), manufactured by Wako Pure Chemical Co.) were dissolved in 405 parts of 1-methoxy-2-propanol was dropwise added into the vessel over a period of 2.5 hours. The mixture was agitated further for 2 hours under heating at 70° C. The obtained reaction liquid was poured into 4000 parts of water, and the resulting solid was separated by filtration and dried under vacuum to obtain a methacrylic acid/allyl methacrylate/benzyl methacrylate terpolymer (terpolymer 4). The weight-average molecular weight of the terpolymer was 36,000 (converted as polystyrene).

Workup

  1. temperatureheated under a nitrogen flow so that the internal temperature of the vessel
  2. customwas 70° C
  3. additionwas dropwise added into the vessel over a period of 2.5 hours
  4. customThe obtained reaction liquid
  5. customthe resulting solid was separated by filtration
  6. customdried under vacuum

Sources & evidence

ORD record
ord-4f03a3498d164e9b835fd39fff5b2871
Source dataset
uspto-grants-2006_05
Patent number
US07041416B2

Reaction notes

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