HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-methyl-6,7-dihydro-1-benzothiophen-4(5H)-one → 5-Methyl-4,5,6,7-tetrahydro-1-benzothiophen-4-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-methyl-6,7-dihydro-1-benzothiophen-4(5H)-one | HCID 15411508 | — |
| Reactant | 4,5,6,7-Tetrahydro-1-benzofuran-4-amine | HCID 18525171 | — |
| Product | 5-Methyl-4,5,6,7-tetrahydro-1-benzothiophen-4-amine | HCID 20348929 | — |
Reaction Steps
Following the procedure for the preparation of 4,5,6,7-tetrahydro-1-benzofuran-4-amine but substituting 5-methyl-6,7-dihydro-1-benzothiophen-4(5H)-one and making non-critical variations provided the title compound as a oil: 1H NMR (400 MHz, CDCl3) δ) 7.12–6.99, 4.13, 3.89, 3.51, 2.86–2.74, 2.13–1.98, 1.75, 1.65, 1.15, 1.07.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07041672B2 |
| Source dataset | uspto-grants-2006_05 |
| ORD ID | ord-9147374737314906b2c3a1a634ef0ddb |
| Source note | uspto-grants-2006_05 |