Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | HCID 17861479 | HCID 17861479 | — |
| Catalyst | HCID 178418778 | HCID 178418778 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 23572096 | HCID 23572096 | 62% |
Reaction Steps
A mixture of 19.8 g of 1-ethylcyclopentyl α-(hydroxymethyl)acrylate, 40.0 g of methyl iodide, 30.0 g of silver (I) oxide and 50 g of N,N-dimethylformamide was stirred at 50° C. for 30 hours. The solids were filtered off, followed by conventional aqueous workup. The solvent was distilled off in vacuo. Purification by distillation (boiling point 53° C./16 Pa) gave 1-ethylcyclopentyl α-(methoxymethyl)acrylate represented by formula (10). The yield was 62%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07041846B2 |
|---|
| Source dataset | uspto-grants-2006_05 |
|---|
| ORD ID | ord-12473d4ae47a4423ac4261091fced7be |
|---|
| Source note | uspto-grants-2006_05 |
|---|
