2,6-Diacetylpyridine → HCID 76843609, compound

HRID 1826188Notes

Reaction equation

HRID 1826188 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([C:10](=O)[CH3:11])[N:5]=1)(=O)[CH3:2].[NH2:13][N:14]1[CH:18]=[CH:17][CH:16]=[CH:15]1>C1(C)C=CC=CC=1>[N:14]1([N:13]=[C:1]([C:4]2[CH:9]=[CH:8][CH:7]=[C:6]([C:10](=[N:13][N:14]3[CH:18]=[CH:17][CH:16]=[CH:15]3)[CH3:11])[N:5]=2)[CH3:2])[CH:18]=[CH:17][CH:16]=[CH:15]1

Participants

4

Reactant 2

HCID 707902,6-DiacetylpyridineHCID 1365891-Aminopyrrole

Product 1

HCID 76843609HCID 76843609, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

2,6-Diacetylpyridine (345 mg, 2.11 mmol) and 1-aminopyrrole (400 mg, 4.87 mmol) were dissolved in 50 ml of toluene. To this solution, molecular sieves (4 Å) were added. After standing for 2 days at room temperature, the mixture was filtered. The solvent was removed in vacuo. The residue was crystallised from ethanol. Yield 350 mg (57%) of diimine 11.

Workup

  1. additionTo this solution, molecular sieves (4 Å) were added
  2. filtrationthe mixture was filtered
  3. customThe solvent was removed in vacuo
  4. customThe residue was crystallised from ethanol

Sources & evidence

ORD record
ord-1b966afdb31e41ff80027ef82e2a3492
Source dataset
uspto-grants-2006_05
Patent number
US07049442B2

Reaction notes

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