HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Aminopyrrole → 2-[1-(2,4,6-Trimethylphenylimino)ethyl]-6-[1-(1-pyrrolylimino)ethyl]pyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Aminopyrrole | HCID 136589 | — |
| Reactant | 1-{6-[(1E)-N-(2,4,6-Trimethylphenyl)ethanimidoyl]pyridin-2-yl}ethan-1-one | HCID 22134468 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2-[1-(2,4,6-Trimethylphenylimino)ethyl]-6-[1-(1-pyrrolylimino)ethyl]pyridine | HCID 73866987 | — |
Reaction Steps
Monoimine (1, 3.0 g, 10.7 mmol) and 1-aminopyrrole (1.0 g, 12.18 mmol) were dissolved in 50 ml of toluene. To this solution, molecular sieves (4 Å) were added. After standing for 40 hours the mixture was filtered. The solvent was removed in vacuo. The residue was crystallised from ethanol. Yield 1.85 g (50%) of mixed diimine 15.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07049442B2 |
| Source dataset | uspto-grants-2006_05 |
| ORD ID | ord-3ca49420e5f34f699b68410e5612d09a |
| Source note | uspto-grants-2006_05 |