M-Cresol → HCID 178428989, compound

HRID 1827626Notes

Reaction equation

[CH3:1][C:2]1[CH:3]=[C:4]([OH:8])[CH:5]=[CH:6][CH:7]=1.[N:9]([O-])=[O:10].[Na+]>>[CH3:1][C:2]1[C:7](=[N:9][OH:10])[CH:6]=[CH:5][C:4](=[O:8])[CH:3]=1

Participants

Reactant 2

HCID 342M-Cresol

HCID 23668193Sodium Nitrite

Product 1

HCID 178428989HCID 178428989, compound

Procedure

3-Methyl-1,4-benzoquinone-4-oxime was prepared by reaction of 3-methylphenol with sodium nitrite under basic conditions by the method of T. Ishikawa et al. described in Tetrahedron 31, 1995, page 8454.

Sources & evidence

ORD record: ord-8b1fceff48664a4faa7ec72f72884b23
Source dataset: uspto-grants-2006_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07056349B2

Reaction notes

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