HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorosuccinimide → HCID 86589689, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorosuccinimide | HCID 31398 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | HCID 86589690 | HCID 86589690 | — |
| Product | HCID 86589689 | HCID 86589689 | 63% |
Reaction Steps
2-(1,1-Dimethyl-2-(N-methoxyimino)ethylaminocarbonyl)-2′-methyl-4′-trifluoromethoxybenzanilide was treated in the same manner as in Example 36, except that the N-bromosuccinimide was replaced with N-chlorosuccinimide, to obtain 3-chloro-2-(1,1-dimethyl-2-(N-methoxyimino)ethylaminocarbonyl)-2′-methyl-4′-trifluoromethoxybenzanilide (yield 63%, melting point 197° C.). Regioselectivity of chlorination into the 3-position was 100%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07057067B2 |
| Source dataset | uspto-grants-2006_06 |
| ORD ID | ord-0c8391b69820495a9cb3acf4fbe8ffb4 |
| Source note | uspto-grants-2006_06 |