HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 21028581, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Hexane | HCID 8058 | — |
| Reactant | HCID 21028579 | HCID 21028579 | — |
| Catalyst | Hydrochloric Acid | HCID 313 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 21028581 | HCID 21028581 | 80% |
Reaction Steps
A few drops of concentrated HCl were added to 5.92 g (15 mmol) VI in 150 ml acetic acid, followed by stirring for 10 h at room temperature. 500 ml water were then added to the reaction solution, followed by repeated extraction with Et2O. The combined organic phases were dried over Na2SO4 and freed from the solvent. Recrystallization from diethylether:n-hexane=4:1 produced 4.21 g (12 mmol, 80%) VII.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07060109B2 |
| Source dataset | uspto-grants-2006_06 |
| ORD ID | ord-29f96919f7a8496780e68acaf1e5d657 |
| Source note | uspto-grants-2006_06 |