Linalool → HCID 24942379, compound

HRID 1828673Notes

Reaction equation

HRID 1828673 reaction equation
C=CC(CCC=C(C)C)(C)O.CC1[C:17]23[CH2:25][C:24]([C:26]([CH3:28])=[O:27])=[C:23]([CH3:29])[CH:19]([C:20]([CH3:22])(C)[CH:16]2[CH2:15]C1)[CH2:18]3>>[C:20](=[C:19]1[CH:17]2[CH2:18][CH2:29][CH:23]1[CH:24]([C:26](=[O:27])[CH3:28])[CH2:25]2)([CH2:16][CH3:15])[CH3:22]

Participants

3

Reactant 2

HCID 6549LinaloolHCID 1070651H-3a,7-Methanoazulene, ethanone deriv.

Product 1

HCID 24942379HCID 24942379, compound

Procedure

4 Isomers in a ratio of 1:1.5:2.9:2.8. Odor description: Woody, floral, linalool, Vertofix, ambery. 1H-NMR (CDCl3, 400 MHz): 3.01–2.44 (m, 3H), 2.15/2.11/2.10 (4s, 3H), 2.11–2.82 (m, 3H), 1.69/1.65/1.63/1.62 (4s, 3H), 1.65–1.20 (m, 5H), 1.02–0.91 (m, 3H) ppm. GC/MS (EI): (major isomer): 192 (M+, 16), 163 (9), 149 (48), 134 (41), 121 (57), 107 (54), 93 (92), 79 (52), 43 (100). IR (atr): 2960s, 2870m, 1707vs, 1453w, 1356m, 1172s, 960w cm−1.

Sources & evidence

ORD record
ord-af1e4b238f814a03828c057d72c96a07
Source dataset
uspto-grants-2006_06
Patent number
US07060664B2

Reaction notes

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