HuagongsheHuagongshe Chemistry Print Report · For research reference only
Propylene Oxide → 2-(1-Cyclohexylpropoxy)-2-methylpropyl propionate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Propylene Oxide | HCID 6378 | — |
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | Propionic anhydride | HCID 31263 | — |
| Reactant | Cyclohexanemethanol, alpha,alpha-dimethyl- | HCID 85531 | — |
| Reactant | 1-Cyclohexylethanol | HCID 137829 | — |
| Reactant | HCID 178478990 | HCID 178478990 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2-(1-Cyclohexylpropoxy)-2-methylpropyl propionate | HCID 68435557 | — |
Reaction Steps
The following compounds of Examples 6 and 7 were prepared analogously to the methods described under Example 1, except that the alcohol component used was 2-cyclohexyl-2-propanol, which can be prepared from cyclohexylmagnesium chloride and acetone by a Grignard reaction, instead of 1-cyclohexyl-1-ethanol. Furthermore, propylene oxide was used instead of isobutylene oxide. The esterification was carried out with acetic anhydride (Example 6) or propionic anhydride (Example 7). Thus, only the spectroscopic data are given at this point:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07064102B2 |
| Source dataset | uspto-grants-2006_06 |
| ORD ID | ord-49d23bbc67fc4dd8ac83b1cac993692c |
| Source note | uspto-grants-2006_06 |