HCID 21317639, compound → 8-Methylsulfonyl-12-hydroxy-13,13-dimethyl-10-heptadecynoic acid

HRID 1833469Notes

Reaction equation

HRID 1833469 reaction equation
CS(C(CCCC(OC(=O)C)CCCCC)CCCCCCC(OC)=O)(=O)=O.[CH3:29][S:30]([CH:33]([CH2:44][C:45]#[C:46][CH:47]([O:55]C(=O)C)[C:48]([CH3:54])([CH3:53])[CH2:49][CH2:50][CH2:51][CH3:52])[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][C:40]([O:42]C)=[O:41])(=[O:32])=[O:31]>>[CH3:29][S:30]([CH:33]([CH2:44][C:45]#[C:46][CH:47]([OH:55])[C:48]([CH3:54])([CH3:53])[CH2:49][CH2:50][CH2:51][CH3:52])[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][C:40]([OH:42])=[O:41])(=[O:31])=[O:32]

Participants

3

Reactant 2

HCID 21317639HCID 21317639, compoundHCID 21317665HCID 21317665, compound

Product 1

HCID 213176218-Methylsulfonyl-12-hydroxy-13,13-dimethyl-10-heptadecynoic acid

Procedure

The synthesis of this compound is carried out by the procedure of Example 3, Step E, except that methyl 8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent amount of methyl 8-methylsulfonyl-12-acetoxy-13,13-dimethyl-10-heptadecynoate.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-0ad1afb386504b32a7718d584730aba6
Source dataset
uspto-grants-1978_01
Patent number
US04066675

Reaction notes

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