HCID 21317589, compound → HCID 21317672, compound

HRID 1833474Notes

Reaction equation

HRID 1833474 reaction equation
COC([C:5]([S:29]([CH3:32])(=[O:31])=[O:30])([CH2:16][CH2:17][CH2:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])=O.COC(C(S(C)(=O)=O)(CCCC(OC(=O)C)CCCC=C)CCCCCCC(OC)=O)=O>>[CH3:32][S:29]([CH:5]([CH2:16][CH2:17][CH2:18][CH:19]([O:25][C:26](=[O:28])[CH3:27])[CH2:20][CH2:21][CH2:22][CH:23]=[CH2:24])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])(=[O:30])=[O:31]

Participants

3

Reactant 2

HCID 21317589HCID 21317589, compoundHCID 21317603Methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate

Product 1

HCID 21317672HCID 21317672, compound

Procedure

The synthesis of this compound is carried out as in Example 3, Step D, except that the methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxyheptadecanoate is replaced by an equivalent quantity of methyl 8-methoxycarbonyl-8-methylsulfonyl-12-acetoxy-16-heptadecenoate.

Workup

  1. customThe synthesis of this compound

Sources & evidence

ORD record
ord-b76ca47bf34d411ab0b16feb342c6c94
Source dataset
uspto-grants-1978_01
Patent number
US04066675

Reaction notes

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