Bisphenol A → HCID 21387928, compound

HRID 1833872Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:11]2[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=2)([CH3:10])[CH3:9])=[CH:4][CH:3]=1.[CH3:18][CH2:19][CH2:20][CH:21]1[O:23][CH2:22]1>>[OH:23][CH:21]([CH2:20][CH2:19][CH3:18])[CH2:22][O:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]([C:11]2[CH:12]=[CH:13][C:14]([O:17][CH2:7][CH:2]([OH:1])[CH2:3][CH2:4][CH3:5])=[CH:15][CH:16]=2)([CH3:10])[CH3:9])=[CH:6][CH:7]=1

Participants

Reactant 2

HCID 6623Bisphenol A2×

HCID 13853Oxirane, 2-propyl-

Product 1

HCID 21387928HCID 21387928, compound

Procedure

Bis-phenol A, that is 2,2-di(p-hydroxy-phenyl-)propane, was reacted in known manner with an excess of pentene - 1,2-oxide. The product, the mixture of diastereisomers, 2,2-bis-(p-(β-hydroxy-pentoxy-)phenyl)propane was obtained as a yellow-brown, semisolid mass, which was obtained as a colorless substance by distillation b.p.:192°-210° C/O .005 mm. The OH-equivalent was 207.

Workup

additionThe product, the mixture of diastereisomers

Sources & evidence

ORD record: ord-6d559fcac6694eeb83eda980ebb5fecd
Source dataset: uspto-grants-1978_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04067853

Reaction notes

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