HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylamine → Benzenepropanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylamine | HCID 7622 | — |
| Reactant | Allyl Alcohol | HCID 7858 | — |
| Reactant | Iodobenzene | HCID 11575 | — |
| Reactant | Tridecane | HCID 12388 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | Diphenyl Ether | HCID 7583 | — |
| Product | Benzenepropanal | HCID 7707 | 62% |
Reaction Steps
0.1 g Palladium acetate, 10.2 g iodobenzene, 4.4 g allyl alcohol, 9.3 g tributylamine were heated together with 20 ml diphenyl ether as solvent and 2 g tridecane as internal standard. After 45 minutes at 135° the iodobenzene was 91% reacted to produce 62% 3-phenylpropanal and 13% hydratropic aldehyde based on conversion.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04070374 |
| Source dataset | uspto-grants-1978_01 |
| ORD ID | ord-8403b14b0c2c43eeb5af9b661f6d16bf |
| Source note | uspto-grants-1978_01 |