HRID1834944

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C[C@@H]1CC2=CC(=O)C[C@H](C)[C@]2(CO)[C@H]2CC[C@]3(C)[C@@H](O)CC[C@H]3[C@H]12

HCID70585453

未命名化合物

结构：CC(C)=O.O=S(=O)(O)O.[O]=[Cr](=[O])=[O]

HCID131709961

未命名化合物

PRODUCTS

生成物

结构：C[C@@H]1CC2=CC(=O)C[C@H](C)[C@]2(C=O)[C@H]2CC[C@]3(C)C(=O)CC[C@H]3[C@H]12

HCID53879340

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID180

Acetone

C3H6O

2 次

PROCEDURE

实验过程

To a solution of 17β,19-dihydroxy-1α,7α-dimethyl-4-androsten-3-one in acetone at 20° C. is added two equivalents of Jones Reagent and the mixture stirred for 30 minutes. The acetone layer is poured onto water with vigorous stirring. The crystals are removed by suction filtration and air dried. Crystallization from an acetone-hexane solution yields 1α,7α-dimethyl-4-androstene-3,17,19-trione.

WORKUP

后处理

customThe crystals are removed by suction filtration and air
customdried
customCrystallization from an acetone-hexane solution