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HRID1834996

反应详情

EQUATION

反应方程式

HRID 1834996 的结构方程式

REACTANTS

反应物

2
结构：CC(=O)O.C[C@]12CC[C@H]3[C@@H](CC[C@H]4C[C@@H](O[Si](c5ccccc5)(c5ccccc5)c5ccccc5)CC[C@@]43CO)[C@@H]1CCC2=O
HCID86735436

未命名化合物

结构：COC[C@]12[C@@H](CC[C@H]3[C@@H]4CC[C@H](OC(C)=O)[C@@]4(C)CC[C@@H]31)C[C@@H](OC(C)=O)C[C@H]2C
HCID86735437

未命名化合物

PRODUCTS

生成物

2
结构：C[C@]12CC[C@H]3[C@@H](CC[C@H]4C[C@@H](O[Si](c5ccccc5)(c5ccccc5)c5ccccc5)CC[C@@]43CO)[C@@H]1CCC2=O
HCID22801524

未命名化合物

结构：COC[C@]12[C@@H](CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]31)C[C@@H](O)C[C@H]2C
HCID70614537

未命名化合物

PROCEDURE

实验过程

Substituting 3β-(1'-cyclopentenyloxy)-19-hydroxy-5α-androstan-17-one acetate, 19-hydroxy-3β-triphenylsiloxy-5α-androstan-17-one acetate and 19-methoxy-1β-methyl-5α-androstane-3β,17β-diol diacetate for the 19-hydroxy-3β-(2'-tetrahydropyranyloxy)-5α-androstan-17-one acetate above results in the preparation of 3β-(1'-cyclopentenyl-oxy)-19-hydroxy-5α-androstan-17-one, 19-hydroxy-3β-triphenylsiloxy-5α-androstan-17-one and 19-methoxy-1β-methyl-5α-androstane-3β,17β-diol, respectively.