Sulfuric Acid → HCID 13634833, compound

HRID 1835445Notes

Reaction equation

HRID 1835445 reaction equation
[K+].[C:2]([C:4]([C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([N+:15]([O-:17])=[O:16])[CH:10]=1)=[CH:5][C:6]([O-:8])=[O:7])#N.S(=O)(=O)(O)[OH:19]>C(O)=O.O>[N+:15]([C:11]1[CH:10]=[C:9]([C:4]2[C:2](=[O:19])[O:7][C:6](=[O:8])[CH:5]=2)[CH:14]=[CH:13][CH:12]=1)([O-:17])=[O:16]

Participants

5

Reactant 2

HCID 1118Sulfuric AcidHCID 69901207HCID 69901207, compound

Product 1

HCID 13634833HCID 13634833, compound

Reagents, catalysts & solvents 2

HCID 284Formic AcidSolventHCID 962WaterSolvent2×

Procedure

To a suspension of.3-cyano-3-(3-nitro-phenyl)-acrylic acid potassium salt (1.28 g) in formic acid (10 ml) and water (1 ml) was added sulfuric acid (1 ml), and the mixture was refluxed for 3 hours. After cooling, the mixte was poured into water. The resulting precipitate was collected by filtration and dried to give 3-(3-nitrophenyl)-furan-2,5-dione(0.69 g).

Workup

  1. additionTo a suspension of
  2. temperaturethe mixture was refluxed for 3 hours
  3. temperatureAfter cooling
  4. filtrationThe resulting precipitate was collected by filtration
  5. customdried

Sources & evidence

ORD record
ord-abedb34834994618965553e8cd6f0b63
Source dataset
uspto-grants-2004_08
Patent number
US06770667B1

Reaction notes

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