HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acrylate → Methyl 4-nitrononanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acrylate | HCID 8821 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1-Nitrohexane | HCID 12589 | — |
| Catalyst | Trioctylmethylammonium chloride | HCID 21218 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Methyl 4-nitrononanoate | HCID 10632556 | — |
Reaction Steps
Ex-31a) A suspension of ethyl acrylate, 1-nitrohexane, K2CO3, and Aliquat 336 (6 drops) is sonicated for 5 h. To the reaction is added Et2O. The reaction mixture is filtered, extracted with brine, dried over Na2SO4 (anhydrous), filtered, and concentrated under reduced pressure to give a yellow liquid. The product is purified by column chromatography to give methyl 4-nitrononanoate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06774126B2 |
| Source dataset | uspto-grants-2004_08 |
| ORD ID | ord-defac01f58d6412198e26f96884e1d86 |
| Source note | uspto-grants-2004_08 |