HCID 13927424, compound → HCID 23517408, compound

HRID 1835967Notes

Reaction equation

HRID 1835967 reaction equation
[CH2:1]([C:3]([OH:10])([CH2:8][CH3:9])[CH2:4][CH2:5][CH2:6][OH:7])[CH3:2].[CH:11]12[CH:20]3[CH2:21][CH:17]([CH:18]=[CH:19]3)[CH:16]1[CH:15]1[CH2:22][CH:12]2[CH:13]([C:23](OC)=[O:24])[CH2:14]1>>[CH:11]12[CH:20]3[CH2:21][CH:17]([CH:18]=[CH:19]3)[CH:16]1[CH:15]1[CH2:22][CH:12]2[CH:13]([C:23]([O:7][CH2:6][CH2:5][CH2:4][C:3]([CH2:8][CH3:9])([OH:10])[CH2:1][CH3:2])=[O:24])[CH2:14]1

Participants

3

Reactant 2

HCID 13927424HCID 13927424, compoundHCID 20753552HCID 20753552, compound

Product 1

HCID 23517408HCID 23517408, compoundYield 89%

Procedure

By following the procedure of Synthesis Example 2 except that 4-ethyl-1,4-hexanediol was used instead of 4-methyl-1,4-pentanediol and methyl 8-tetracyclo-[4.4.0.12,5.17,10]dodecene-3-carboxylate used instead of methyl 5-norbornene-2-carboxylate, there was obtained 4-ethyl-4-hydroxyhexyl 8-tetracyclo[4.4.0.12,5.17,10]dodecene-3-carboxylate. Yield 89%.

Sources & evidence

ORD record
ord-efb9f081a1fb4c53869c01d57d1f8fe3
Source dataset
uspto-grants-2004_08
Patent number
US06774258B2

Reaction notes

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