5-methyl-1,5-hexanediol → HCID 22179005, compound

HRID 1835969Notes

Reaction equation

HRID 1835969 reaction equation
[CH3:1][C:2]([OH:9])([CH3:8])[CH2:3][CH2:4][CH2:5][CH2:6][OH:7].[CH:10]12[CH2:16][CH:13]([CH:14]=[CH:15]1)[CH2:12][CH:11]2[CH2:17][CH2:18][CH2:19][C:20](OC)=[O:21]>>[CH:10]12[CH2:16][CH:13]([CH:14]=[CH:15]1)[CH2:12][CH:11]2[CH2:17][CH2:18][CH2:19][C:20]([O:7][CH2:6][CH2:5][CH2:4][CH2:3][C:2]([OH:9])([CH3:8])[CH3:1])=[O:21]

Participants

3

Reactant 2

HCID 111372105-methyl-1,5-hexanediolHCID 22179012HCID 22179012, compound

Product 1

HCID 22179005HCID 22179005, compoundYield 92%

Procedure

By following the procedure of Synthesis Example 2 except that 5-methyl-1,5-hexanediol was used instead of 4-methyl-1,4-pentanediol and methyl 4-(5-norbornen-2-yl)butyrate used instead of methyl 5-norbornene-2-carboxylate, there was obtained 5-hydroxy-5-methylhexyl 4-(5-norbornen-2-yl)butyrate. Yield 92%.

Sources & evidence

ORD record
ord-0537a6d4be104d7cbb61000589a8a329
Source dataset
uspto-grants-2004_08
Patent number
US06774258B2

Reaction notes

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