HRID1836066

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14798

Sodium Hydroxide

HNaO

结构：CC(C)(C)CC(C)(C)c1ccc(O)c(C(C)(C)c2ccccc2)c1

HCID22644018

Phenol, 2-(1-methyl-1-phenylethyl)-4-(1,1,3,3-tetramethylbutyl)-

C23H32O

结构：N#[N+]c1ccc(-c2ccccc2)cc1[N+](=O)[O-].O=S(=O)([O-])O

HCID85822691

未命名化合物

结构：CC(C)(C)CC(C)(C)c1cc(N=Nc2ccc(-c3ccccc3)cc2[N+](=O)[O-])c(O)c(-c2ccccc2)c1

HCID136377676

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)CC(C)(C)c1cc(N=Nc2ccc(-c3ccccc3)cc2[N+](=O)[O-])c(O)c(C(C)(C)c2ccccc2)c1

HCID135678145

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

The procedure of Example 1 (D) is followed using sodium hydroxide (4 g, 0.1 mol), methanol (100 mL), 4-phenyl-2-nitrobenzenediazonium hydrogen sulfate (16 g, 0.034 mol) and 2-α-cumyl-4-tert-octylphenol (8.1 g, 0.028 mol) to give the title compound as a dark red solid melting at 176-179° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7d359ab160084f0ea111d3159f73a675
来源数据集: uspto-grants-2004_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06774238B2
来源说明: uspto-grants-2004_08

反应 SMILES

OC1C(C2C=CC=CC=2)=CC(C(CC(C)(C)C)(C)C)=CC=1N=NC1C=CC(C2C=CC=CC=2)=CC=1[N+]([O-])=O.[OH-].[Na+].S([O-])(O)(=O)=O.[C:46]1([C:52]2[CH:57]=[CH:56][C:55]([N+:58]#[N:59])=[C:54]([N+:60]([O-:62])=[O:61])[CH:53]=2)[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=1.[C:63]([C:72]1[CH:77]=[C:76]([C:78]([CH2:81][C:82]([CH3:85])([CH3:84])[CH3:83])([CH3:80])[CH3:79])[CH:75]=[CH:74][C:73]=1[OH:86])([C:66]1[CH:71]=[CH:70][CH:69]=[CH:68][CH:67]=1)([CH3:65])[CH3:64]>CO>[OH:86][C:73]1[C:72]([C:63]([C:66]2[CH:67]=[CH:68][CH:69]=[CH:70][CH:71]=2)([CH3:65])[CH3:64])=[CH:77][C:76]([C:78]([CH2:81][C:82]([CH3:85])([CH3:84])[CH3:83])([CH3:80])[CH3:79])=[CH:75][C:74]=1[N:59]=[N:58][C:55]1[CH:56]=[CH:57][C:52]([C:46]2[CH:47]=[CH:48][CH:49]=[CH:50][CH:51]=2)=[CH:53][C:54]=1[N+:60]([O-:62])=[O:61]