HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-(Cyclohex-1-en-1-yl)-3-methoxybenzene → (R,R)-1-(3-Methoxy-phenyl)-7-oxa-bicyclo[4.1.0]heptane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-(Cyclohex-1-en-1-yl)-3-methoxybenzene | HCID 265818 | — |
| Reactant | (S,S)-1-(3-Methoxy-phenyl)-7-oxa-bicyclo[4.1.0]heptane | HCID 23519630 | — |
| Product | (R,R)-1-(3-Methoxy-phenyl)-7-oxa-bicyclo[4.1.0]heptane | HCID 59097191 | — |
Reaction Steps
Prepared in a similar manner from 1-Cyclohex-1-enyl-3-methoxy-benzene as described for (S,S)-1-(3-Methoxy-phenyl)-7-oxa-bicyclo[4.1.0]heptane above using (S,S)—Mn(salen) as catalyst. The enantiomeric excess was 92.36%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06780891B2 |
| Source dataset | uspto-grants-2004_08 |
| ORD ID | ord-b717e4b13e854ead9350b79f593befd9 |
| Source note | uspto-grants-2004_08 |