HCID 10712156, compound → HCID 11045622, compound

HRID 1837839Notes

Reaction equation

HRID 1837839 reaction equation
FC(F)(F)S(OCCCOS(C(F)(F)F)(=O)=O)(=O)=O.[F:20][C:21]([F:41])([F:40])[S:22]([O:25][CH:26]1CCCC[CH:27]1[O:32][S:33]([C:36]([F:39])([F:38])[F:37])(=[O:35])=[O:34])(=[O:24])=[O:23]>>[F:38][C:36]([F:37])([F:39])[S:33]([O:32][CH2:27][CH2:26][O:25][S:22]([C:21]([F:41])([F:40])[F:20])(=[O:24])=[O:23])(=[O:34])=[O:35]

Participants

3

Reactant 2

HCID 10712156HCID 10712156, compoundHCID 13214238HCID 13214238, compound

Product 1

HCID 11045622HCID 11045622, compound

Procedure

Preparation and handling of organometallic compounds were carried out in the absence of air and moisture under argon (Schlenk technique or glove box). All solvents required were purged with argon and dried over molecular sieves before use. 1,2-Bistrifluoromethylsulfonyloxyethane was synthesized as described by Lindner, Ekkehard; Au, Guenter von; Eberle, Hans-Juergen; Chem.Ber.; 114; 2; 1981; 810-813. The preparations of 1,3-bistrifluoromethylsulfonyloxypropane and 1,2-bistrifluoromethylsulfonyloxycyclohexane were carried out analogously. The indenes used were prepared as described in WO 9840331.

Workup

  1. customAll solvents required were purged with argon
  2. customdried over molecular sieves before use

Sources & evidence

ORD record
ord-54da5617482745b8b3c80696c4db1602
Source dataset
uspto-grants-2004_08
Patent number
US06784305B2

Reaction notes

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