D-(-)-Fructose → Lyxose

HRID 1838039Notes

Reaction equation

[O:1]=[CH:2][C@H:3]([C@H:5]([C@@H:7]([C@@H:9](CO)[OH:10])[OH:8])[OH:6])[OH:4].OCC([C@H]([C@@H]([C@@H](CO)O)O)O)=O.OCC([C@H]([C@@H](CO)O)O)=O>>[O:1]=[CH:2][C@H:3]([C@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4]

Participants

Reactant 3

HCID 5984D-(-)-Fructose

HCID 161658Demannose

HCID 5289590D-Xylulose

Product 1

HCID 65550Lyxose

Procedure

It was found that 21.9 mmol/l mannose, 74.4 mmol/l fructose, 70.4 mmol/l xylulose and 24.4 mmol/l lyxose were formed and accumulated in the respective reaction mixtures.

Sources & evidence

ORD record: ord-c708205cf93648cfadac8dfbf9a6e01b
Source dataset: uspto-grants-2004_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06673581B1

Reaction notes

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