HCID 15188896, compound → HCID 168011492, compound

HRID 1838703Notes

Reaction equation

HRID 1838703 reaction equation
[C:1]([C-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1)#[CH:2].[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13].[C-:14]1([C:19]#[C:20][C:21]2[CH:26]=[CH:25][CH:24]=[C:23](I)[CH:22]=2)[CH:18]=[CH:17][CH:16]=[CH:15]1.[CH-:28]1[CH:32]=[CH:31][CH:30]=[CH:29]1.[Fe+2]>>[C-:3]1([C:1]#[C:2][C:23]2[CH:24]=[CH:25][CH:26]=[C:21]([C:20]#[C:19][C-:14]3[CH:18]=[CH:17][CH:16]=[CH:15]3)[CH:22]=2)[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13].[CH-:28]1[CH:32]=[CH:31][CH:30]=[CH:29]1.[Fe+2:13]

Participants

3

Reactant 2

HCID 15188896HCID 15188896, compound2×HCID 178506545HCID 178506545, compound

Product 1

HCID 168011492HCID 168011492, compound

Procedure

Ethynylferrocene 500 was reacted with 1,3-diiodobenzene 502 to form 1-(ferrocenylethynyl)-3-iodobenzene 504. Sufficient ethynylferrocene 500 was present such that the second step of the reaction immediately proceeded. 1-(Ferrocenylethynyl)-3-iodobenzene 504 reacted with ethynylferrocene 514 to form 1,3-bis(ferrocenylethynyl) benzene 516. The reaction procedure is shown in FIG. 5.

Sources & evidence

ORD record
ord-32c2944e894d4009ad9afb568af6b8bf
Source dataset
uspto-grants-2004_01
Patent number
US06673953B2

Reaction notes

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