Sodium Hydroxide → Cyclopropanecarboxamide

HRID 1841659Notes

Reaction equation

HRID 1841659 reaction equation
[OH-:1].[Na+:2].[Cl:3][O-].[Na+].[CH:6]1([C:9]([NH2:11])=[O:10])[CH2:8][CH2:7]1>O>[OH-:10].[Na+:2].[O-:1][Cl:3].[Na+:2].[CH:6]1([C:9]([NH2:11])=[O:10])[CH2:8][CH2:7]1

Participants

6

Reactant 3

HCID 14798Sodium HydroxideHCID 80376CyclopropanecarboxamideHCID 23665760Sodium Hypochlorite

Product 2

HCID 80376CyclopropanecarboxamideHCID 86647248NaOH NaClO

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

To feed the reactor, an NaOH/NaOCl solution was prepared by slowly adding 434.8 g of 50 wt. % aqueous NaOH to 1533 g of 12.02 wt % aqueous sodium hypochlorite (by analysis) with constant chilling and stirring in an ice-water bath. A cyclopropanecarboxamide solution was prepared by dissolving 187 g (2.20 mol) of cyclopropanecarboxamide in 913 g of water to produce a 17 wt. % solution of cyclopropanecarboxamide.

Workup

  1. temperaturewith constant chilling
  2. customA cyclopropanecarboxamide solution was prepared

Sources & evidence

ORD record
ord-27c92f73b4514180af05fb5f6d2b095e
Source dataset
uspto-grants-2004_01
Patent number
US06683216B1

Reaction notes

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