HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-(5-hydroxy-4-oxo-4H-pyran-2-ylmethyl)-benzene sulfonamide → N-(5-Hydroxy-4-oxo-4H-pyran-2-ylmethyl)-3-methyl-benzenesulfonamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-(5-hydroxy-4-oxo-4H-pyran-2-ylmethyl)-benzene sulfonamide | HCID 86725691 | — |
| Reactant | N-(5-Benzyloxy-4-oxo-4H-pyran-2-ylmethyl)-3-methyl-benzenesulfonamide | HCID 86725714 | — |
| Product | N-(5-Hydroxy-4-oxo-4H-pyran-2-ylmethyl)-3-methyl-benzenesulfonamide | HCID 86725715 | 81.5% |
Reaction Steps
N-(5-Hydroxy-4-oxo-4H-pyran-2-ylmethyl)-3-methyl-benzenesulfonamide (8-04) (15 g, crude) was synthesized as a light brown solid from N-(5-benzyloxy-4-oxo-4H-pyran-2-ylmethyl)-3-methyl-benzenesulfonamide (7-04) (24.0 g, 62.33 mmol) following the procedure described for N-(5-hydroxy-4-oxo-4H-pyran-2-ylmethyl)-benzenesulfonamide (8-01).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08952039B2 |
| Source dataset | uspto-grants-2015_02 |
| ORD ID | ord-d176c1bc55fb4e899497e4b1044f2e4c |
| Source note | uspto-grants-2015_02 |