HRID1846877

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：NC(c1cc(=O)c(OCc2ccccc2)c(C(=O)O)o1)S(=O)(=O)c1ccccc1

HCID86725695

未命名化合物

结构：Cc1ccc(S(=O)(=O)NCc2cc(=O)c(OCc3ccccc3)c(C=O)o2)cc1

HCID86725733

未命名化合物

PRODUCTS

生成物

结构：Cc1ccc(S(=O)(=O)NCc2cc(=O)c(OCc3ccccc3)c(C(=O)O)o2)cc1

HCID86725734

未命名化合物

收率 80.14%

PROCEDURE

实验过程

3-Benzyloxy-4-oxo-6-[(toluene-4-sulfonylamino)-methyl]-4H-pyran-2-carboxylic acid (12-06) (2.0 g, 80.14%) was synthesized as a white solid from N-(5-benzyloxy-6-formyl-4-oxo-4H-pyran-2-ylmethyl)-4-methyl-benzenesulfonamide (11-06) (2.4 g, 5.81 mmol) following the procedure described for 6-(benzenesulfonylamino-methyl)-3-benzyloxy-4-oxo-4H-pyran-2-carboxylic acid (12-01).