HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → (E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Dimethylacetamide | HCID 31374 | — |
| Reactant | 5-Chloro-2,4-dinitrotoluene | HCID 253802 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | (E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine | HCID 59129321 | 72.4% |
Reaction Conditions
| Temperature | 100 °C |
|---|
Reaction Steps
A mixture of 1-chloro-5-methyl-2,4-dinitro-benzene (11.6 g, 50.0 mmol), DMA (11.9 g, 100 mmol) in DMF (50 mL) was heated at 100° C. for 4 h. The solution was cooled and poured into water. The precipitated red solid was collected by filtration, washed with water, and dried to give (E)-2-(5-chloro-2,4-dinitrophenyl)-N,N-dimethylethenamine (9.84 g, 72%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08952050B2 |
| Source dataset | uspto-grants-2015_02 |
| ORD ID | ord-87cc6ba52a42471dbce3fb8def79d386 |
| Source note | uspto-grants-2015_02 |